首页> 外文OA文献 >New insights into ligand inductive effects on the stability of Mn12 single molecule magnets. Synthesis, magnetic and thermal characterization of complex [Mn12O12(O2CC≡CH)16(H2O)4].3H2O and the corresponding manganese(II) propiolate [Mn3(O2CC≡CH)6(H2O)4]2H2O derived by thermolysis reaction.

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New insights into ligand inductive effects on the stability of Mn12 single molecule magnets. Synthesis, magnetic and thermal characterization of complex [Mn12O12(O2CC≡CH)16(H2O)4].3H2O and the corresponding manganese(II) propiolate [Mn3(O2CC≡CH)6(H2O)4]2H2O derived by thermolysis reaction.

机译：关于配体感应作用对Mn12单分子磁体稳定性的新见解。通过热解反应得到的[Mn12O12（O2CC≡CH）16（H2O）4] .3H2O和相应的丙酸锰（II）[Mn3（O2CC≡CH）6（H2O）4] 2H2O的合成，磁性和热表征。

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International audience

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Gómez-Segura, Jordi; Campo, Javier; Imaz, Inhar; Wurst, Klaus; Veciana, Jaume; Gerbier, Philippe; Ruiz-Molina, Daniel;
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年度 2007
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1. New insights into the thermal stability of Mn12 clusters:The case of complex [Mn12O12(O2CC ident to CH)16(H2O)4]-3H2O and its thermolysis derived [Mn3(O2CC ident to CH)6(H2O)4]-2H2O complex [J] . Jordi Gomez-Segura, Javier Campo, Inhar Imaz Dalton transactions: An international journal of inorganic chemistry . 2007,第23期

机译：Mn12团簇热稳定性的新见解：复杂的[Mn12O12（O2CC与CH相同）16（H2O）4] -3H2O的情况及其热解衍生[Mn3（O2CC与CH6（H2O）4相同）]-2H2O复杂
2. Trihaloacetic acids: an investigation of steric and inductive ligand effects on the synthesis of [Mn12O12(O2CCX3)(16)(H2O)(4)] single-molecule magnets [J] . Gomez-Segura J, Lhotel E, Paulsen C, New Journal of Chemistry . 2005,第3期

机译：三卤乙酸：对[Mn12O12（O2CCX3）（16）（H2O）（4）]单分子磁体合成的空间和感应配体作用的研究
3. Synthesis, Structure, and Spectroscopic and Magnetic Characterization of [Mn12O12(O2CCH2But)16(MeOH)4]·MeOH, a Mn12 Single-Molecule Magnet with True Axial Symmetry [J] . Christos Lampropoulos, †, ∥ Muralee Murugesu, Inorganic Chemistry . 2013,第1期

机译：具有真正轴对称性的Mn12单分子磁体[Mn12O12（O2CCH2But）16（MeOH）4]·MeOH的合成，结构以及光谱和磁性表征
4. Synthesis and Characterization of the Complexes of Pentane-24-dione with Nickel(II) and Cobalt(III): Ni(acac)2·0.5CH3OH and Co(acac)2NO3·2H2O (acac = Pentane-24-dione) [O] . Yang Qu, Hai-Liang Zhu, Zhong-Lu You, 2004

机译：戊烷-24-二酮与镍（II）和钴（III）：Ni（acac）2·0.5CH3OH和Co（acac）2NO3·2H2O（acac = Pentane- 24-二酮）
5. New insights into the thermal stability of Mn12 clusters: The case of complex [Mn12O12(O2CC≡CH)16(H2O)4]·3H2O and its thermolysis derived [Mn3(O2CC≡CH)6(H2O)4]·2H2O complex [O] . Gómez-Segura, Jordi, Campo, Javier, Imaz, Inhar, 2017

机译：Mn12团簇热稳定性的新见解：[Mn12O12（O2CC≡CH）16（H2O）4]·3H2O配合物及其热解衍生的[Mn3（O2CC≡CH）6（H2O）4]·2H2O配合物

New insights into ligand inductive effects on the stability of Mn12 single molecule magnets. Synthesis, magnetic and thermal characterization of complex [Mn12O12(O2CC≡CH)16(H2O)4].3H2O and the corresponding manganese(II) propiolate [Mn3(O2CC≡CH)6(H2O)4]2H2O derived by thermolysis reaction.

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